Explore Bwin's detailed preview for Olympiakos Piraeus vs PSV Eindhoven in the UEFA Champions League. Stats, odds, predictions, and lineups for the 20:00 GMT match.

Match Details
Fixture: Olympiakos Piraeus vs PSV Eindhoven
Date: Tuesday, 04 November 2025
Kick-off: 20:00 GMT
Venue: Georgios Karaiskakis Stadium
Olympiakos Piraeus, coming off heavy defeats against Barcelona and Arsenal, will look to regain confidence at home. Their recent draw against Pafos suggests a defensive approach might be adopted, focusing on counter-attacks led by the likes of Podence and Kaabi. PSV Eindhoven, on the other hand, have shown offensive prowess with a 6-2 win over Napoli, indicating they could dominate possession and press high up the pitch.
However, PSV's inconsistent form, including a loss to Union St. Gilloise and a draw against Bayer Leverkusen, suggests vulnerabilities that Olympiakos could exploit. The Greek side's resilience at home, as seen in their draw against Pafos, could be crucial. Expect a tightly contested match with Olympiakos potentially capitalising on PSV's defensive lapses.
Olympiakos Piraeus have struggled recently, suffering heavy defeats against Barcelona and Arsenal. These losses highlight a need for defensive improvements, which could be a focus in their upcoming match. Their draw against Pafos at home suggests they can be solid defensively when needed, which might be key against PSV.
Loss: 1-6 vs Barcelona (A)
Loss: 0-2 vs Arsenal (A)
Draw: 0-0 vs Pafos (H)
PSV Eindhoven have shown a mix of results, with a convincing win against Napoli but also a loss to Union St. Gilloise at home. Their ability to score goals, as seen in the Napoli game, indicates a strong attacking threat. However, their inconsistency, particularly in defense, could be a concern against Olympiakos.
Win: 6-2 vs Napoli (H)
Draw: 1-1 vs Bayer Leverkusen (A)
Loss: 1-3 vs Union St. Gilloise (H)
In their previous encounters, Olympiakos and PSV have had closely contested matches. Olympiakos won 4-2 at home, while PSV secured a 2-1 victory in the return leg. These results suggest a competitive fixture, with both teams capable of scoring and winning.
PSV Eindhoven 2-1 Olympiakos Piraeus (25 Feb 2021) - UEFA Europa League
Olympiakos Piraeus 4-2 PSV Eindhoven (18 Feb 2021) - UEFA Europa League
Gustavo Mancha (Inactive) - Out
K. Angelakis (Inactive) - Out
N. Botis (Inactive) - Out
R. Cabella (Inactive) - Out
R. Vezo (Inactive) - Out
Rodinei (Calf Injury) - Out
Y. Yazici (Inactive) - Out
Ruben Van Bommel (Knee) - Doubt
Alassane Pléa (Knee) - Doubt
Predicted lineup: Tzolakis (GK), Costinha (DF), Retsos (DF), Pirola (DF), Ortega (DF), Hezze (MF), Garcia (MF), Martins (MF), Chiquinho (MF), Podence (MF), Kaabi (AT)
Olympiakos will rely on the midfield creativity of Podence and Martins to unlock PSV's defense, while their backline, led by Retsos and Pirola, will need to be solid to counter PSV's attacking threats.
Predicted lineup: Kovar (GK), Flamingo (DF), Schouten (DF), Gasiorowski (DF), Salah-Eddine (DF), Junior (MF), Veerman (MF), Man (MF), Saibari (MF), Perisic (MF), Til (AT)
PSV's attacking line, spearheaded by Til and supported by the creative duo of Saibari and Perisic, will aim to break down Olympiakos' defense, while Gasiorowski and Schouten will be crucial in maintaining defensive stability.
Bwin brings you the most exciting offers to enhance your experience.
For the best UEFA Champions League outright predictions, explore our guide.
Odds and market details are accurate as of the time of publication.